Quote from Osayidan;40895:
Passwords are md5+salt, so we can't get them.
There's tools to log in to a user account while logged in as admin, without password changing, but I never understood the reason for them, the admins can just look at your profile on the admin panel to get everything they could ever need, and to modify anything that needs modifying.
There's more risk of someone packet sniffing on your LAN getting your password than an admin of a vbulletin forum, unless it's https.
The "Log in as user" plugin by Valter was created so that administrators could check forums permissions and functions, though I have also used it for moderation (Investigation into member harassment).
As for MD5/Salt, vBulletin is secure by itself, but that doesn't mean theres no chance of a database leak (For any site). You should never use the same password on multiple sites.